How Ice Melts: Longstanding Mystery Solved

posted: 30 June 2005 02:00 pm ET

: Fig1 Bright field image shows premelting at a grain boundary within a crystal. The image shows a two dimensional cross-section of the three dimensional colloidal crystal. The crystal orientation in the upper part of the image is different from the lower part. A grain boundary separates these two sections of crystal. The circles in the image represent the position of each spherical particle, and the central color of each circle represents the degree of positional fluctuation of each colloidal particle. Violet (red) represents the most (least) particle movement. Credit: Arjun Yodh, Penn State
: 050630_melting3_02.jpg Test-tube containing a suspension of NIPA particles at high volume fraction. The sample is in its crystalline (solid) phase. The crystals are iridescent. Green light is diffracted from the crystal. The uniform color indicates that the sample contains one crystalline domain to certain extent. Credit: Arjun Yodh, Penn State

Until now, scientists could not explain why ice cubes in your drink melt. They've known the basics, but the details remained elusive.

A breakthrough new study, announced today, supports a leading theory that melting starts when the fundamental structure of matter begins to crack.

Melting is considered a basic phenomenon in physics. An understanding of how it works is crucial to gaining a firm grasp on the physical world.

"Yet major details about the mechanisms that drive the melting of an ice cube are missing," said Arjun Yodh of the University of Pennsylvania. "Superficially, the principle is straightforward. As a solid heats up, molecules within the ice acquire more energy and jiggle around more, driving the transition from a solid to a liquid. This is true in part, but reality is richer and more complex."

The problem is that the earliest phase of melting has never been seen. Scientists can't see the atoms involved because they are so small and because they are hidden in the structure of solid material.

So Yodh's team made some big atoms. Specifically, they made see-through crystals that are like small beads and are visible in an optical microscope.

"The spheres swell or collapse significantly with small changes in temperature, and they exhibit other useful properties that allow them to behave like enormous versions of atoms for the purpose of our experiment," said Ahmed Alsayed, a University of Pennsylvania doctoral student and lead author of a paper on the results in the July 1 issue of the journal Science.

A premelting occurs in spots where atoms within solid crystals are not perfectly aligned, and they begin to move. The changes are seen in pictures taken as the material was heated. The imperfections are much like the differences seen in wood grain, the scientists said.

"These motions then spread into the more ordered parts of the crystal," Alsayed said. "We could see that the amount of premelting depended on the type of crystal defect and on the distance from the defect."

Nature could inspire technology as the process is investigated further.

"The existence of premelting inside solid materials implies that liquids exist within crystals before their melting temperature is reached," Yodh said. "Understanding this effect will provide insight for the design of strong materials that are more or less impervious to temperature changes and could also apply to our theories of how natural materials, such as water, evolve in our environment."