Rare, 'rule-breaking' quasicrystal found in chunk of 'fossilized' lightning
A type of crystal that breaks the rules of ordinary crystallography has been found in a tube of melted sand from Nebraska.
A tube of "fossilized lightning" from Nebraska's Sandhills holds a rare type of quasicrystal that had previously only been found in meteorites and at atomic bomb test sites.
Quasicrystals are materials that break the traditional rules of crystallography. Before they were first reported in 1984, scientists thought materials could either be crystalline — with symmetrical, repeating patterns — or amorphous, meaning randomly arranged and disordered. In addition, scientists believed crystals could only be symmetrical a limited number of times when rotated around an axis — two, three, four or six times.
Quasicrystals break those rules. They're put together in an ordered pattern, but that pattern does repeat. They also have rotational symmetries that no ordinary crystal can achieve. A quasicrystal with icosahedral symmetry, for example, can display five-fold symmetry around six different lines of rotation.
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Quasicrystals were first discovered in the laboratory. In 2012, however, Paul Steinhardt, a theoretical physicist at Princeton University, and Luca Bindi, a geoscientist at the University of Florence in Italy, announced the discovery of a natural quasicrystal in a meteorite that fell on the Kamchatka Peninsula in northeastern Russia. The researchers then created more quasicrystals in the lab by mimicking the high temperatures and high pressures that might be found when rocky bodies collide. They then turned to another place where a very rapid transition to high temperature and high pressure occurred: the Trinity atomic bomb test site in New Mexico. There, they found more quasicrystals in minerals from beneath where the atomic bomb exploded.
"For this reason, I started to think of other materials formed in similar conditions. And I thought of fulgurites, materials formed by lightning strikes," Bindi told Live Science in an email.
Fulgurites form when lightning hits sand, fusing together the grains in a gnarly, branching tube of glass. Bindi collected multiple fulgurites in his search for quasicrystals. The one that held this rare form of matter came from the Sandhills of Nebraska, near the village of Hyannis. This area of Nebraska is made up of grass-covered sand dunes.
The fulgurite was found near a power line that went down in a storm in 2008. In total, it was about 6.6 feet (2 meters) long and up to 3.1 inches (8 centimeters) in diameter. No one witnessed the event, so the researchers aren't sure whether lightning struck the power line and created the fulgurite, or whether the line went down in the wind and created the fulgurite with its own electrical discharge.
Either way, the resulting branched glass contained a mixture of materials from the sand and the metals in the electrical line, including manganese, silicon, chromium, aluminum and nickel. To meld these materials, the temperature of the sand must have briefly reached at least 3,110 degrees Fahrenheit (1,710 degrees Celsius), the researchers reported Dec. 27 in the journal Proceedings of the National Academy of Sciences.
Hunting for quasicrystals
Using a scanning electron microscope, Bindi, Steinhardt and their colleagues found a 12-sided, 12-angled crystal with 12-fold symmetry embedded in the fulgurite. Quasicrystals with this sort of symmetry are even rarer than quasicrystals in general, the researchers wrote in their paper; quasicrystals with 10-fold symmetry or icosahedral symmetry are more common.
The discovery points to new places to look for natural quasicrystals, Bindi said.
"It demonstrates that transient extreme pressure-temperature conditions are suitable for the synthesis of quasicrystals," he said. Other potential places to find quasicrystals, he said, might be in impact glasses formed when large meteorites or asteroids hit Earth, or in parts of the moon's surface that have been hit by asteroids.
Editor's note: Updated at 4 p.m. EST to clarify that the discovery of quasicrystals was first reported in a scientific publication in 1984. The discovery itself, made by National Institute of Standards and Technology scientist Dan Shechtman, occurred in 1982.
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Stephanie Pappas is a contributing writer for Live Science, covering topics ranging from geoscience to archaeology to the human brain and behavior. She was previously a senior writer for Live Science but is now a freelancer based in Denver, Colorado, and regularly contributes to Scientific American and The Monitor, the monthly magazine of the American Psychological Association. Stephanie received a bachelor's degree in psychology from the University of South Carolina and a graduate certificate in science communication from the University of California, Santa Cruz.
By Sascha Pare