On Very Thin Ice

(College Park, MD) -- For the first time, scientists have obtained pictures of ice only a few nanometers thick in the act of forming bulk ice at the coldest of temperatures. The new images, showing ice sheets about 50,000 times thinner than a human hair, add to our knowledge of water, that remarkable molecular substance that is common on Earth, and found in significant amounts in other places around the solar system.

Most scientists think of ice as forming from six-sided tiny crystals. The six-fold symmetry, the shape of classic snowflakes, comes from the way water molecules fit together. But at very low temperatures, close to absolute zero -- the coldest conceivable state of matter -- water molecules don’t behave the way they do at warmer temperatures.

Like people first waking from a sound sleep, water molecules in this chilly environment can’t move very well. If you spray them onto a platinum surface they tend to stay where they land. If you keep adding water, the molecules form a solid called amorphous ice, with all of the molecules sticking together wherever they can. Because of the extreme cold, the molecules don’t have enough energy to line up to form a crystalline array.

Raise the temperature a bit, just above 120 degrees Kelvin (-243 degrees Fahrenheit), and now the molecules have a chance to creep around enough to start assembling a proper crystal. But these little blobs still aren’t in the familiar hexagonal shape. Instead the water molecules form a cubic crystal structure. To form common ice, with its hexagonal structure, a little bit more warmth is required – a still-frosty 160 kelvin (-189 Fahrenheit).

Konrad Thürmer and Norman C. Bartelt, two scientists at Sandia National Laboratory in Livermore, California, were interested in exploring the early formation of ice as part of their research into the initial stages of the growth of crystal films.

The device they used to make the ice pictures is called a scanning tunneling microscope (STM), which works by positioning a narrow needle tip near the sample and then allowing a tiny electrical current to flow across the gap. And just as the up-and-down movement of a stylus in the groove of an old-style vinyl record can read the music encoded in the wavy surface of the record, so the voltage applied to the machine that controls the height of the STM tip as the tip is scanned across the face of the ice sheet can be used to form an image of the ice.

The result is the images of ice crystallites much smaller than previously seen. Earlier attempts to image very thin ice sheets with an STM failed because it is difficult to conduct electricity through ice. But this time the scientists got just enough electricity to flow – partly by cranking up the voltage, and partly by making a stepping-stone path for the electricity to follow through the ice.

What did they find? When the ice film was really thin, only about 1 nanometer thick on average, the water molecules formed into little islands of ice. When the thickness reached 4 or 5 nanometers, the ice started to form larger joined chunks. They believe that when one tiny crystallite adding molecules on a downward going slope meets with a crystallite with an upward-going slope, the two structures start to pivot around each other. This accounts for the somewhat corkscrew appearance of the patchwork quilt of merging ice sheets.

The new work was reported in this month’s issue of the journal Physical Review B.

--Phil Schewe

This article was provided by Inside Science News Service, which is supported by the American Institute of Physics. ISNS contributor Phil Schewe is a senior science writer with the American Institute of Physics.

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Image Credit: Sandia National Laboratory