Scientists Make Ice Hotter Than Boiling Water

Scientists have turned water into ice in nanoseconds, which means really, really fast. That's not the most interesting part, though. The ice is hotter than boiling water.

The experiment was done at the Sandia National Laboratories' huge Z machine, which generates temperatures hotter than the sun (setting a record here on Earth) and where researchers test what we know about those plain vanilla "phases" in textbooks: solid, liquid and gas.

"The three phases of water as we know them—cold ice, room temperature liquid, and hot vapor—are actually only a small part of water’s repertory of states," said Sandia researcher Daniel Dolan. "Compressing water customarily heats it. But under extreme compression, it is easier for dense water to enter its solid phase [ice] than maintain the more energetic liquid phase [water]."

Ice is odd. Most things shrink when they get cold, and so they take up less space as solids than as liquids. But regular ice, of course, takes up more space than water. A simple experiment of putting a (preferably cheap) full water bottle in the freeze overnight will demonstrate this.

In the new experiment, however, the volume of "water shrank abruptly and discontinuously, consistent with the formation of almost every known form of ice except the ordinary kind," according to a Sandia statement Thursday.

Apparently, there are at least 11 other types of ice that most of us don't know about. They're classified by how they behave at certain temperatures and pressures. You might have heard of one: Supercooled water can be below 32 degrees but not frozen.

Problem is, scientists don't know the specifics of all these states. Hence the Sandia research.

Dolan said the work "helps us understand materials at extreme conditions."

He was surprised by how quickly the water froze. Rapid compression—around 70,000 times normal atmospheric pressure in a tiny fraction of a second—caused the rapid freezing, he figures. When the pressure was relieved, the ice melted.

"Apparently it’s virtually impossible to keep water from freezing at pressures beyond 70,000 atmospheres," Dolan said.

That's good to know, for people who are trying to solve water's many mysteries.